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PVC Membranes: Traditional Formula or New Innovation

October 5, 2016

Since their entrance into the
commercial roofing market in
the 1960s, polyvinyl chloride
(PVC) membranes have experienced
tremendous growth and
acceptance, along with many
beneficial changes, both in formulation
and in manufacturing processes. Are these
changes positive? Which type of PVC is
better to use: one that is comprised of traditional
formulations and manufacturing
methods, or one that has been produced
with an improved formulation on innovative
manufacturing lines?
Many are fixated only on the formulation,
but the process of manufacture can
have a negative or positive impact on the
long-term performance of PVC. As with
baking, the recipe for PVC has instructions
for the ingredients, as well as for the
type, quantity, and order of mixing. The
recipe also includes instructions on equipment,
length of time, and temperature.
Formulation by itself does not guarantee a
performing product; the manufacturing process
also affects the long-term performance
of the end product.
There are differing opinions on these
issues, and data presented from both sides.
This article will discuss the advancements
in PVC formulation and manufacturing
technology.
There are currently three primary methods
used for manufacturing PVC membranes;
they are, in order from newest
to oldest: extrusion, calendering, and
spread-coating. Let’s first review the differences
in these processes.
Spread-coating, the original manufacturing
process used for PVC, starts with a
carrier sheet (internal reinforcement) that
is transported through a production line
where viscous liquid PVC is spread onto the
carrier to create a thin coating of PVC. The
carrier, now spread-coated with PVC, travels
through extremely hot, long ovens where
the PVC is cured. To coat the underside, the
material is flipped and the process is started
over (Figure 1).
Many manufacturers of PVC eventually
moved from spread-coating to a newer process
called calendering. The calendering
process is initiated with the compound
(formulation) in solid form of powder or
pellets, which are mixed, forced through an
extruder, and then immediately squeezed
between heated calender rollers, which
press the compound into the desired thickness.
The PVC is then allowed to cool and
is rolled up for packaging. This calendering
process exposes the formulation to
long periods of heat
exposure, as does
the spread-coating
process. Changing
from the spreadcoating
operation,
which uses the
viscous liquid formulation,
to the
calendering or extrusion
process,
which utilizes the
solid compound, requires
a formulation
change.
The newest and
most innovative
process for manufacturing PVC is the extrusion
process, in which the PVC formulation
is heated to an appropriate softening point
and forced through an extruder and out a
flat die. Fabric is introduced at this point
and processed through a roll stack, where
the fabric is encapsulated between the top
and bottom extruded plies under pressure.
In contrast to the calendering process, the
thickness of the membrane is determined by
the extruder die, not by roller compression
as in the calendering process. The rollers
in the extrusion process simply press the
material together and cool the membrane.
(See Figure 2.)
While the extrusion process has been
around for decades, it has made the greatest
technological advancements (when compared
to other manufacturing processes)
over time. Extrusion is the manufacturing
process that most innovative manufacturers
use, and the one we believe has been proven
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Figure 1 – Knife-over roll coating line.
to produce higher-performing material due
to decreased manufacturing stress on the
material. In fact, newer extruders are much
more efficient and effective than the extruder
equipment of just ten years ago. There
are many reasons why we believe using the
most up-to-date extrusion process is the
ideal option for manufacturing PVC.
“With today’s technological advances
and the ability to precisely monitor
and control temperatures, pressures, and
thicknesses, the process of manufacturing
PVC roofing materials has significantly
improved,” said Bill Knuf, Carlisle
Construction Materials’ Greenville, IL, plant
manager. “These changes have made a PVC
sheet that looks better, performs better, and
should provide building owners with many
years of great service.”
One of the key features of the newer extrusion
process is the integrated control package
it utilizes. This computer software fully ties
all of the pieces of the manufacturing operation
together, including fabric unwinding,
extrusion, web forming, web handling, and
material wind-up (Figure 3). This is important
because in order for the manufacturing
process to run smoothly and accurately, all
of these steps have to take place at just the
right time; and in order for that to happen,
every operational process must be precisely
controlled from start to finish. This is one of
the main advantages of using a newer extrusion
system, as many older extrusion systems
do not have fully integrated software and can
experience breakdowns in the manufacturing
operation and potential inconsistencies in
product quality.
OC T O B E R 2 0 1 6 I N T E R F A C E • 2 9
353 Christian Street, Unit 13, Oxford, CT 06478  Phone 203-262-9245  Lindareith@trinityerd.com
Trinty|ERD is pleased to
announce the opening of its new
wind testing laboratory in
Oxford, CT., the latest expansion
in its service offering. Having conducted static uplift testing of
commercial roofing systems for over 20 years, Trinity|ERD now offers
its customers testing to the CAN/CSA A123.21 dynamic wind uplift
resistance standard, which is the only codified wind uplift standard in
the National Building Code of Canada (NBCC 2015).
 One of two laboratories in the world that is ISO 17025 accredited
(IAS TL-689) using equipment commissioned through the National
Research Council of Canada (NRC).
 UL Client Test Data Program Participant (DA2667) for UL TGIK
(static) and TGFY7 (dynamic) uplift certification listings.
 12×24 ft chamber size to mirror historical static testing.
 Criticality analysis for selection of critical components.
 Also ISO 17025 accredited for static wind uplift standards codified
in the International Building Code and Florida Building Code.
– ANSI/FM Standard 4474
– UL 1897
– Florida HVHZ TAS 114, Appendix D & J
 Also ISO 17025 accredited for field (in-situ) static wind uplift
standards.
– ANSI/SPRI IA-1
– ASTM E907
– FM Loss Prevention Data Sheet 1-52
– Florida HVHZ TAS 124
Figure 2 – Typical extrusion line.
The two greatest advantages provided
by integrated process control software are
repeatability of performance and traceability
of past product. The idea of repeatability
of performance takes into account the fact
that your PVC membrane performance consists
of both a formula and a manufacturing
process. The formulation and the manufacturing
process are equally important for the
production of a high-quality membrane. You
need to know the variables in both the formulation
and the process in order to create
a consistent product. Manufacturers’ newer
computer-integrated extrusion processes
provide just that; they monitor both the formulation
and the manufacturing process to
ensure that the end result is a consistently
produced and performing PVC membrane.
The second advantage
of integrated process
control software
is traceability of past
product. At any point
in time, computer-integrated
systems are monitoring
over 10,000 data
points that are collected
from the entire production
line. This provides
manufacturers with the
ability to define specific
performance criteria for the PVC membrane
and consistently match those criteria
through each roll of membrane produced. It
also means the ability to easily identify and
correct production errors as they occur in
the manufacturing process, ensuring that
defective product does not reach the end of
the production line—let alone the customer—
while also facilitating future improvements
in product and longer-term performance.
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January 2017 Miscellaneous (bldg. envel.) October 14, 2016
February 2017 Codes and standards November 15, 2016
March 2017 Trends in wall & roof design December 15, 2016
April 2017 Air and vapor control January 13, 2017
May/June 2017 Convention review February 15, 2017
July 2017 Testing April 14, 2017
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Figure 3 – Computer-integrated controls for process control.
Figure 4 – High-speed blender and cooler.
Another aspect of the extrusion process
is that it takes into account the nature
of PVC material, minimizing the heat and
tension to which the membrane is exposed
during the manufacturing process. Both
excessive temperatures and long exposures
to heat (which can create free radicals and
start the breakdown process) and tension
are detrimental to long-term performance.
Newer extrusion processes are unique
because every roller in the entire production
line features load cells that measure and
equalize the tension that is placed on the
material across its entire width throughout
the process. Many of the older lines do not
have this extensive measurement of tension.
New extrusion processes also reduce the
amount and length of heat to which the PVC
is exposed. Unlike older extrusion technologies
and spread-coat methods, new extrusion
processes extrude material at its exact
thickness, which means that the rollers on
the manufacturing line are not heated (which
causes longer exposure to excess heat), but
rather cooled. This not only reduces the heat
exposure to the PVC, but also provides significant
energy savings, making new extrusion
line technology more energy-efficient.
Older PVC extrusion lines do not have the
ability to extrude to exact thicknesses, so
they extrude a bank of material into a heated
calender roll stack, which is a form of modified
calender operation.
One of the most important factors in
producing consistent, high-quality roofing
membranes is the ability to monitor the
thickness of the product, both in real
time and over historical production periods.
Newer PVC extrusion lines feature a
measuring device that monitors the material
thickness across the membrane’s entire
width, automatically adjusting the die when
necessary to ensure consistent quality and
thickness. Because these data are stored,
the integrated process control package can
monitor the consistency of material thickness
over time, not just for one roll or one
batch of product.
The blending process is another vital
element of PVC production. New, state-ofthe-
art compounding and blending towers
(Figure 4) utilize a complete component
delivery system, which requires no manual
weighing or adding of materials, eliminating
the potential for human error. Many calender
operations have hand-weighed and packaged
ingredients, which are hand-fed into mixers
or Banburys. The formula’s materials are
stored in a blend tower (Figure 5) that moves
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You. Us. The project.
800 255 4255 PROSOCO.COM
and measures solids and liquids into weigh
scales in the correct formula proportions.
The materials are then blended, with speeds
and temperatures increasing throughout the
blending process to trigger the addition of
different materials at different times for
optimal blending. The entire process is monitored
and registered by the software system,
which means that if any material does not
make it into the blender, the computer will
notice and make sure that the missing material
is added before production continues.
This ensures that batches of product do
not proceed down the entire production line
before an incorrect formulation is caught.
This blending process also
monitors the material inventory
levels, signaling when
inventory is diminishing and
more materials are needed,
thus increasing efficiencies
in inventory control and
reducing backorders.
As can be seen, the
extrusion process is complex
and intricate, yet also
refined and efficient—one of
the best commercial roofing
technologies available
today. While there are many
ways to manufacture PVC,
we believe data demonstrate
that extrusion is the
most efficient and accurate
method for producing
a high-quality, consistent,
and durable rooftop.
One of the important
aspects of PVC production is
that formulas have changed
over time, due to government
regulations or chemical
manufacturers being
sold or going out of business
entirely. Manufacturing processes have
improved with new equipment and greatly
enhanced controls. I was told recently by a
supplier of extrusion equipment, “Ten years
ago, 75% of our engineers were mechanical;
today, 75% of our engineers are electrical,”
emphasizing the development of improved
process control and automation.
Advancements in integrated process
controls help to ensure consistency in manufacturing.
As the industry has moved
from spread-coating to calendering, and
more recently to extrusion, formulas have
necessarily changed to optimize membrane
production for each of these methods. All
formulas for PVC membrane manufacturing
include common ingredients, such as PVC
polymer, plasticizers, stabilizers, process
aids, flame retardants, biocides, heat stabilizers,
and pigments. However, while there
are common ingredients across the board,
it is essential that some of these ingredients
change according to the manufacturing
process being used. For instance, it is
not possible to extrude a PVC membrane
with the same formula used in the spreadcoating
process. When processes are
changed, formulations must change in order
to produce a consistent, top-notch product.
The global environment is also harsher than
it was 20 years ago, demanding increased
performance.
While there are varied methods for
manufacturing PVC roofing membranes,
new technology and the most up-to-date
formulations and manufacturing processes
available should produce a consistent,
high-quality, and longer-lasting PVC rooftop
covering.
Figure 5 – Ten-story blending and compounding tower
structure.
John C. Greko is
currently PVC
Product Manager
for Carlisle Construction
Materials
and first started
in the PVC roofing
business in 1982.
He previously was
VP of engineering
and QA for a
roofing manufacturer,
was a faculty
member of RIEI, a Certified Roofing
Instructor for BOCA, a member of ASTM,
director for SPRI, and a consulting editor for
Architecture magazine. Greko holds four
patents for products and/or processes used
in single-ply roofing.
John C. Greko
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Apropos of this issue of RCI Interface, which is dedicated to product manufacturing,
Manufacturing Day in the United States is celebrated this year on October 7. Some
Canadian companies have also joined in marking the day. The recognition is intended to be
a celebration of modern manufacturing to inspire the next generation of manufacturers.
Manufacturers are encouraged to open their doors and show what manufacturing is. It
is sponsored by the Fabricators & Manufacturers Association International (FMA), the
National Association of Manufacturers, the Manufacturing Extension Partnership (MEP),
and the Manufacturing Institute. For more information, visit www.mfgday.com.
October 7 Is Manufacturing Day